Strong Light-Matter Coupling in Carbon Nanotubes as a Route to Exciton Brightening

We show that strong light-matter coupling can be used to overcome a long standing problem that has prevented efficient optical emission from carbon nanotubes. The luminescence from the nominally bright exciton states of carbon nanotubes is quenched due to the fast nonradiative scattering to the dark exciton state having a lower energy. We present a theoretical analysis to show that by placing carbon nanotubes in an optical microcavity the bright exctonic state may be split into two hybrid exciton-polariton states, while the dark state remains unaltered. For sufficiently strong coupling between the bright exciton and the cavity, we show that the energy of the lower polariton may be pushed below that of the dark exciton. This overturning of the relative energies of the bright and dark excitons prevents the dark exciton from quenching the emission. Our resutls pave the way for a new approach to band-engineering the properties of the nanoscale optoelectronic devices.Comment: 35 pages, 5 figures, 6 pages of supplementary materials, 1 supplementary figur

Student preconceptions and reality: A survey exercise to teach wealth inequality

This paper presents a way to enhance student interest and learning when teaching economic inequality. The approach draws on a well-known survey conducted by Norton and Ariely (2011). The approach involves surveying students, asking them to estimate the current level of wealth inequality in the US, and asking them to state their ideal level of wealth inequality. As in Norton and Ariely\u27s survey of a representative sample of Americans, our students underestimated actual wealth inequality and preferred a distribution of wealth for the US that was more equal than any country\u27s distribution. We suggest ways the student survey results can be presented and discussed. We also provide Stata code and an Excel workbook to ease effective classroom presentation of the survey results. This approach to beginning the study of inequality piqued our students\u27 interest and helped them understand how inequality is measured

SeaWiFS calibration and validation plan, volume 3

The Sea-viewing Wide Field-of-view Sensor (SeaWiFS) will be the first ocean-color satellite since the Nimbus-7 Coastal Zone Color Scanner (CZCS), which ceased operation in 1986. Unlike the CZCS, which was designed as a proof-of-concept experiment, SeaWiFS will provide routine global coverage every 2 days and is designed to provide estimates of photosynthetic concentrations of sufficient accuracy for use in quantitative studies of the ocean's primary productivity and biogeochemistry. A review of the CZCS mission is included that describes that data set's limitations and provides justification for a comprehensive SeaWiFS calibration and validation program. To accomplish the SeaWiFS scientific objectives, the sensor's calibration must be constantly monitored, and robust atmospheric corrections and bio-optical algorithms must be developed. The plan incorporates a multi-faceted approach to sensor calibration using a combination of vicarious (based on in situ observations) and onboard calibration techniques. Because of budget constraints and the limited availability of ship resources, the development of the operational algorithms (atmospheric and bio-optical) will rely heavily on collaborations with the Earth Observing System (EOS), the Moderate Resolution Imaging Spectrometer (MODIS) oceans team, and projects sponsored by other agencies, e.g., the U.S. Navy and the National Science Foundation (NSF). Other elements of the plan include the routine quality control of input ancillary data (e.g., surface wind, surface pressure, ozone concentration, etc.) used in the processing and verification of the level-0 (raw) data to level-1 (calibrated radiances), level-2 (derived products), and level-3 (gridded and averaged derived data) products

SeaWiFS technical report series. Volume 10: Modeling of the SeaWiFS solar and lunar observations

Post-launch stability monitoring of the Sea-viewing Wide Field-of-view Sensor (SeaWifs) will include periodic sweeps of both an onboard solar diffuser plate and the moon. The diffuser views will provide short-term checks and the lunar views will monitor long-term trends in the instrument's radiometric stability. Models of the expected sensor response to these observations were created on the SeaWiFS computer at the National Aeronautics and Space Administration's (NASA) Goddard Space Flight Center (GSFC) using the Interactive Data Language (IDL) utility with a graphical user interface (GUI). The solar model uses the area of intersecting circles to simulate the ramping of sensor response while viewing the diffuser. This model is compared with preflight laboratory scans of the solar diffuser. The lunar model reads a high-resolution lunar image as input. The observations of the moon are simulated with a bright target recovery algorithm that includes ramping and ringing functions. Tests using the lunar model indicate that the integrated radiance of the entire lunar surface provides a more stable quantity than the mean of radiances from centralized pixels. The lunar model is compared to ground-based scans by the SeaWiFS instrument of a full moon in December 1992. Quality assurance and trend analyses routines for calibration and for telemetry data are also discussed

Light outcoupling efficiency of top-emitting organic light-emitting diodes

Copyright © 2004 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 84 (2004) and may be found at http://link.aip.org/link/?APPLAB/84/2986/1We report results obtained from modeling the light outcoupling efficiency of top–emitting organic light-emitting diode (OLED) structures and compare them with results from conventional substrate-emitting structures. We investigate two types of emissive material, small molecule and conjugated polymers, and study three different cathode materials; aluminum, silver, and calcium. We show that top-emitting OLEDs may have outcoupling efficiencies comparable to their substrate-emitting counterparts, and that the choice of cathode material is critical to the optical performance of the device

Coupled surface plasmon-polariton mediated photoluminescence from a top-emitting organic light-emitting structure

Copyright © 2004 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in Applied Physics Letters 85 (2004) and may be found at http://link.aip.org/link/?APPLAB/85/182/1We report strong photoluminescence from a top-emitting organic light-emitting structure where emission takes place through a thin (55 nm) silver film. We show that this emission is mediated via coupled surface plasmon-polariton modes. Our results show that the addition of a dielectric grating to otherwise planar structures, such as surface-emitting organic light-emitting diodes, may offer a way to increase the external efficiency of top-emitting organic light-emitting diodes

Di- and Trinuclear Mixed-Valence Copper Amidinate Complexes from Reduction of Iodine

Molecular examples of mixed-valence copper complexes through chemical oxidation are rare but invoked in the mechanism of substrate activation, especially oxygen, in copper-containing enzymes. To examine the cooperative chemistry between two metals in close proximity to each other we began studying the reactivity of a dinuclear Cu(I) amidinate complex. The reaction of [(2,6-Me2C6H3N)2C(H)]2Cu2, 1, with I2 in tetrahydrofuran (THF), CH3CN, and toluene affords three new mixed-valence copper complexes [(2,6-Me2C6H3N)2C(H)]2Cu2(μ2-I3)(THF)2, 2, [(2,6-Me2C6H3N)2C(H)]2Cu2(μ2-I) (NCMe)2, 3, and [(2,6-Me2C6H3N)2C(H)]3Cu3(μ3-I)2, 4, respectively. The first two compounds were characterized by UV-vis and electron paramagnetic resonance spectroscopies, and their molecular structure was determined by X-ray crystallography. Both di- and trinuclear mixed-valence intermediates were characterized for the reaction of compound 1 to compound 4, and the molecular structure of 4 was determined by X-ray crystallography. The electronic structure of each of these complexes was also investigated using density functional theory

MEF2C regulates outflow tract alignment and transcriptional control of Tdgf1

Congenital heart defects are the most common birth defects in humans, and those that affect the proper alignment of the outflow tracts and septation of the ventricles are a highly significant cause of morbidity and mortality in infants. A late differentiating population of cardiac progenitors, referred to as the anterior second heart field (AHF), gives rise to the outflow tract and the majority of the right ventricle and provides an embryological context for understanding cardiac outflow tract alignment and membranous ventricular septal defects. However, the transcriptional pathways controlling AHF development and their roles in congenital heart defects remain incompletely elucidated. Here, we inactivated the gene encoding the transcription factor MEF2C in the AHF in mice. Loss of Mef2c function in the AHF results in a spectrum of outflow tract alignment defects ranging from overriding aorta to double-outlet right ventricle and dextro-transposition of the great arteries. We identify Tdgf1, which encodes a Nodal co-receptor (also known as Cripto), as a direct transcriptional target of MEF2C in the outflow tract via an AHFrestricted Tdgf1 enhancer. Importantly, both the MEF2C and TDGF1 genes are associated with congenital heart defects in humans. Thus, these studies establish a direct transcriptional pathway between the core cardiac transcription factor MEF2C and the human congenital heart disease gene TDGF1. Moreover, we found a range of outflow tract alignment defects resulting from a single genetic lesion, supporting the idea that AHF-derived outflow tract alignment defects may constitute an embryological spectrum rather than distinct anomalies

Using improved power electronics modeling and turbine control to improve wind turbine reliability

Improving offshore wind turbine reliability is a key industry goal to improve the availability of this renewable energy generation source. The semiconductor devices in the wind turbine power converter are traditionally considered as the most sensitive and important components to achieve this and managing their thermomechanical stressing is vital, since this is one of their principal long-term aging mechanisms. Conventional deterministic reliability prediction methods used in industrial applications are not suitable for wind turbine applications, due to the stochastic nature of the wind speed. This paper develops an electrothermal model of the power devices, which is integrated with a wind turbine system model for the investigation of power converter thermal cycling under various operating conditions. The model has been developed to eliminate the problems of pulse width modulation switching, substantially reducing simulation time. The model is used to improve the current controller tuning method to reduce thermal stresses suffered by the converter during a grid fault. The model is finally used to design a control method to alleviate a key problem of the doubly fed induction generator—severe thermal cycling caused during operation near synchronous speed